The incomplete thermal SCO observed in the dinuclear species

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anabolic steroids 928KbAbstractStructural studies of several iron complexes that show spin crossover (SCO) properties are presented and intrinsic links between the structure and properties have been established for these systems. X ray diffraction experiments of samples under extremes of temperature and pressure and after irradiation with laser light have been performed to characterise the structure of these various compounds. The incomplete thermal SCO observed in the dinuclear species [2 4,4′ bipy]2MeOH has been investigated, revealing a complex series of crystallographic phase transitions that result in a material with a mixture of high spin (HS) and low spin (LS) states that displays long range order at low temperature. anabolic steroids

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